Comparative study of leachate treatment by coagulation-flocculation process using iron-based coagulants: A case study on Souk-Ahras city

Abstract

The objective of this study was to evaluate the coagulation-flocculation process in the clarification of leachate from the landfill Technical Center of Souk-Ahras cityusing three coagulants based on iron: ferrous sulfate FeSO4.7H2O; ferrous chloride FeCl2.4H2O and ferric chloride FeCl3. The influence of some parameters namely pH leachate, dose and nature of coagulant and nature of flocculant was studied. The best treatment efficiency was obtained at 20 % of FeCl3 giving a turbidity of4.09 NTU with pH adjustment of the raw leachate at acidic pH (3.5 ± 0.2) before coagulant addition and at a basic pH (7.5 ± 0.2) after addition of coagulant. The iron valence and the nature of anion at which is linked, played a determinant role in the clarification of leachate. The treatments made with ferric chloride in the presence of a flocculant have proved that the starch was more efficient than lime giving abatement rates of 99 % for COD and 85 % for BOD5.